Siloxane dry cleaning composition and process

ABSTRACT

A dry cleaning composition comprising a volatile siloxane and an organic surfactant and, optionally water, and a method for dry cleaning comprising contacting an article with a composition comprising a volatile siloxane and an organic surfactant.

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application claims rights of priority from U.S. Provisional Patent Application Serial No. 60/184,108, filed Feb. 22, 2000.

TECHNICAL FIELD

[0002] The present invention is directed to a dry cleaning composition, more specifically, to a siloxane fluid based composition, for use in dry cleaning and to a dry cleaning process using the composition.

BACKGROUND

[0003] Current dry cleaning technology uses perchloroethylene (“PERC”) or petroleum-based materials as the cleaning solvent. PERC suffers from toxicity and odor issues. The petroleum-based products are not as effective as PERC in cleaning garments.

[0004] Cyclic siloxanes have been reported as spot cleaning solutions, see U.S. Pat. No. 4,685,930, and as dry cleaning fluids in dry cleaning machines, see U.S. Pat. No. 5,942,007. Other patents disclose the use of silicone soaps in petroleum solvents, see JP 09299687, and the use of silicone surfactants in super critical carbon dioxide solutions has been reported, see, for example, U.S. Pat. No. 5,676,705 and Chem. Mark. Rep., 15 December 1997, 252(24), p. 15. Non-volatile silicone oils have also been used as the cleaning solvent requiring removal by a second washing with perfluoroalkane to remove the silicone oil, see JP 06327888.

[0005] Numerous other patents have issued in which siloxanes or organomodified silicones have been present as addenda in PERC or petroleum based dry cleaning solvents, see, for example, WO 9401510; U.S. Pat. No. 4,911,853; No. 4,005,231; No. 4,065,258.

[0006] There is a continued interest in providing an additive or additives to enhance the cleaning ability of silicone based dry cleaning solvents.

SUMMARY OF THE INVENTION

[0007] In a first aspect, the present invention is directed to a dry cleaning composition, comprising a volatile cyclic, linear or branched siloxane and one or more organic surfactants.

[0008] In a second aspect, the present invention is directed to a method for dry cleaning an article, comprising contacting the article with a composition comprising a cyclic, linear or branched siloxane and an organic surfactant which may be chosen from the classes of nonionic, cationic, anionic or amphoteric.

[0009] The process of the present invention exhibits improved performance, such as for example, removal of water soluble stains from the article, for example a garment, being cleaned. The process of the present invention also effectively removes most soluble stains, including oil stains and grease stains.

DETAILED DESCRIPTION OF THE INVENTION

[0010] In a preferred embodiment, the composition comprises, based on 100 parts by weight (“pbw”) of the composition, from greater than 90 pbw to 99.99 pbw, more preferably from 92 pbw to 99.9 pbw and even more preferably from 95 pbw to 99.5 pbw of the siloxane and from 0.001 pbw to less than 10 pbw, more preferably from 0.01 pbw to 8 pbw and even more preferably from 0.1 pbw to 5 pbw of the surfactant. The composition optionally further comprises water, preferably from 0.01 pbw to 15 pbw, more preferably from 0.1 pbw to less than 12 pbw and even more preferably from 0.2 pbw to 10 pbw of water. Preferably, the composition does not include siloxane resins or crosslinking agents.

[0011] In a preferred embodiment, the water may be added as “free” water or may be delivered by an emulsion containing other components such as siloxanes, hydrocarbons, surfactants, or other suitable additives. If the water is delivered by an emulsion, the emulsion may be prepared by either homogenization of the components or by mechanically stirring the mixture.

[0012] Compounds suitable as the linear or branched, volatile siloxane solvent of the present invention are those containing a polysiloxane structure that includes from 2 to 20 silicon atoms. Preferably, the linear or branched, volatile siloxanes are relatively volatile materials, having, for example, a boiling of below about 300° C. point at a pressure of 760 millimeters of mercury (“mm Hg”).

[0013] In a preferred embodiment, the linear or branched, volatile siloxane comprises one or more compounds of the structural formula (I):

M_(2+y+2z)D_(x)T_(y)Q_(z)  (I)

[0014] wherein:

[0015] M is R¹ ₃SiO_(½);

[0016] D is R²R³SiO_({fraction (2/2)});

[0017] T is R⁴SiO_({fraction (3/2)});

[0018] and Q is SiO_({fraction (4/2)})

[0019] R¹, R², R³and R⁴ are each independently a monovalent hydrocarbon radical; and

[0020] x and y are each integers, wherein 0≦x≦10 and 0≦y≦10 and 0≦z≦10.

[0021] Suitable monovalent hydrocarbon groups include acyclic hydrocarbon radicals, monovalent alicyclic hydrocarbon radicals, monovalent and aromatic or fluoro containing hydrocarbon radicals. Preferred monovalent hydrocarbon radicals are monovalent alkyl radicals, monovalent aryl radicals and monovalent aralkyl radicals.

[0022] As used herein, the term “(C₁-C₆)alkyl” means a linear or branched alkyl group containing from 1 to 6 carbons per group, such as, for example, methyl, ethyl, propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, pentyl, hexyl, preferably methyl.

[0023] As used herein, the term “aryl” means a monovalent unsaturated hydrocarbon ring system containing one or more aromatic or fluoro containing rings per group, which may optionally be substituted on the one or more aromatic or fluoro containing rings, preferably with one or more (C₁-C₆)alkyl groups and which, in the case of two or more rings, may be fused rings, including, for example, phenyl, 2,4,6-trimethylphenyl, 2-isopropylmethylphenyl, 1-pentalenyl, naphthyl, anthryl, preferably phenyl.

[0024] As used herein, the term “aralkyl” means an aryl derivative of an alkyl group, preferably a (C₂-C₆)alkyl group, wherein the alkyl portion of the aryl derivative may, optionally, be interrupted by an oxygen atom, such as, for example, phenylethyl, phenylpropyl, 2-(1-naphthyl)ethyl, preferably phenylpropyl, phenyoxypropyl, biphenyloxypropyl.

[0025] In a preferred embodiment, the monovalent hydrocarbon radical is a monovalent (C₁-C₆)alkyl radical, most preferably, methyl.

[0026] In a preferred embodiment, the linear or branched, volatile siloxane comprises one or more of, hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane or hexadecamethylheptasiloxane or methyltris(trimethylsiloxy)silane. In a more highly preferred embodiment, the linear or branched, volatile siloxane of the present invention comprises octamethyltrisiloxane, decamethyltetrasiloxane, or dodecamethylpentasiloxane or methyltris(trimethylsiloxy)silane. In a highly preferred embodiment, the siloxane component of the composition of the present invention consists essentially of decamethyltetrasiloxane.

[0027] Suitable linear or branched volatile siloxanes are made by known methods, such as, for example, hydrolysis and condensation of one or more of tetrachlorosilane, methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, or by isolation of the desired fraction of an equilibrate mixture of hexamethyldisiloxane and octamethylcyclotetrasiloxane or the like and are commercially available.

[0028] Compounds suitable as the cyclic siloxane component of the present invention are those containing a polysiloxane ring structure that includes from 2 to 20 silicon atoms in the ring. Preferably, the linear, volatile siloxanes and cyclic siloxanes are relatively volatile materials, having, for example, a boiling point of below about 300° C. at a pressure of 760 millimeters of mercury (“mm Hg”).

[0029] In a preferred embodiment, the cyclic siloxane component comprises one or more compounds of the structural formula (II):

[0030] wherein:

[0031] R⁵, R⁶, R⁷ and R⁸ are each independently a monovalent hydrocarbon group; and

[0032] a and b are each integers wherein 0≦a≦10 and 0≦b≦10, provided that 3≦(a+b)≦10.

[0033] In a preferred embodiment, the cyclic siloxane comprises one or more of, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetradecamethylcycloheptasiloxane. In a more highly preferred embodiment, the cyclic siloxane of the present invention comprises octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane. In a highly preferred embodiment, the cyclic siloxane component of the composition of the present invention consists essentially of decamethylcyclopentasiloxane.

[0034] Suitable cyclic siloxanes are made by known methods, such as, for example, hydrolysis and condensation of dimethyldichlorosilane and are commercially available.

[0035] The organic surfactant of the present invention comprises one or more surfactants selected from nonionic, cationic, anionic and amphoteric surfactants. In another embodiment, the organic surfactant comprises a mixture of two or more surfactants of the same or different classes, as long as they are compatible, such as, for example, a mixture of two or more nonionic, cationic, anionic or amphoteric surfactants, a mixture of nonionic and cationic surfactants, a mixture of nonionic and anionic surfactants, a mixture of nonionic and amphoteric surfactants, a mixture of cationic and anionic surfactants, a mixture of cationic and amphoteric surfactants, a mixture of anionic and amphoteric surfactants, a mixture of nonionic, cationic and anionic surfactants, a mixture of nonionic, anionic and amphoteric surfactants, a mixture of cationic anionic and amphoteric surfactants, or a mixture of nonionic, cationic, anionic and amphoteric surfactants.

[0036] Compounds suitable for use as the nonionic surfactant of the present invention are those that carry no discrete charge when dissolved in aqueous media. Nonionic surfactants are generally known in the art and include, for example, alkanol amides (such as, for example, coco, lauric, oleic and stearic monoethanolamides, diethanolamides and monoisopropanolamides), amine oxides (such as, for example, polyoxyethylene ethanolamides and polyoxyethylene propanolamides), polyalkylene oxide block copolymers (such as, for example, poly(oxyethylene-co-oxypropylene)), ethoxylated alcohols, (such as, for example, isostearyl polyoxyethylene alcohol, lauryl, cetyl, stearyl, oleyl, tridecyl, trimethylnonyl, isodecyl, tridecyl), ethoxylated alkylphenols (such as, for example, nonylphenol ), ethoxylated amines and ethoxylated amides, ethoxylated fatty acids, ethoxylated fatty esters and ethoxylated fatty oils (such as, for example, mono- and diesters of acids such as lauric, isostearic, pelargonic, oleic, coco, stearic, and ricinoleic, and oils such as castor oil and tall oil), fatty esters, fluorocarbon containing materials, glycerol esters (such as, for example, glycerol monostearate, glycerol monolaurate, glycerol dilaurate, glycerol monoricinoleate, and glycerol oleate), glycol esters (such as, for example, propylene glycol monostearate, ethylene glycol monostearate, ethylene glycol distearate, diethylene glycol monolaurate, diethylene glycol monolaurate, diethylene glycol monooleate, and diethylene glycol stearate), lanolin-based surfactants, monoglycerides, phosphate esters, polysaccharide ethers, propoxylated fatty acids, propoxylated alcohols, and propoxylated alkylphenols, protein-based organic surfactants, sorbitan-based surfactants (such as, for example, sorbitan oleate, sorbitan monolaurate, and sorbitan palmitate), sucrose esters and glucose esters, and thio- and mercapto-based surfactants.

[0037] In a preferred embodiment, one component of the present invention comprises one or more nonionic surfactants according to one or more of the structural formulas III and IV:

R⁹—O—(CH₂—CH₂—O)_(n)—R¹⁰  (III)

R⁹—O—(CH₂—C(CH₃)H—O)_(n)—R¹⁰  (IV)

[0038] wherein:

[0039] R⁹ is a monovalent hydrocarbon group of 1-30 carbons that may be linear, cyclic, branched, unsaturated, aromatic or fluoro containing, R¹⁰ is hydrogen or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic or fluoro containing, and n is from about 1 to about 100, more preferably from about 1 to about 40. In a highly preferred embodiment, R⁹ contains from 2 to about 24 carbons, even more preferably from 8 to 24 carbons, R¹⁰ is H and n is from about 2 to about 20.

[0040] In another preferred embodiment, one component of the present invention comprises one or more nonionic surfactants that may be a sugar-based surfactant according to one or more of the structural formulas V and VI:

[0041] wherein:

[0042] each R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, an oxygenated alkane or other chalcogen containing group. Chalcogens are herein specifically defined as oxygen, sulfur, selenium, tellurium and polonium. These surfactants may also be the open-chain analogs. In a preferred embodiment, R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ are each H or a hydrocarbon group of 1 to 24 carbons, preferably a polyether or ester, even more preferably, one of R¹⁷ and R²⁰ is a hydrocarbon of from 8 to 24 carbons while the other is H or a hydrocarbon of from 1 to 4 carbons, such as —CH₂OH or —CH₂CH₃, and one of R²¹ and R²⁵ is H or a hydrocarbon of from 8 to 24 carbons while the other is a hydrocarbon of from 1 to 4 carbons, such as —CH₂OH or —CH₂CH₃. In another preferred embodiment, the surfactant or surfactants are chosen from sucrose esters, glucose esters, monoglycerides, polysaccharide ethers and sorbitan-based surfactants.

[0043] In another preferred embodiment, one component of the present invention comprises one or more nonionic surfactants that may be an amine-based or phosphate ester-based surfactant according to one or more of the structural formulas VII and VIII:

[0044] wherein:

[0045] each R¹¹, R¹², R¹³, R¹⁴, R¹⁵, and R¹⁶ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic, fluoro containing, an oxygenated alkane or other chalcogen containing group. In a preferred embodiment, two of R¹¹, R¹² and R¹³, are H or hydrocarbon groups of 1 to 4 carbons, and one is a hydrocarbon group of from 8 to 24 carbons, and R¹⁴ and R¹⁵ are either H or hydrocarbon groups of from 1 to 4 carbons while R¹⁶ is a hydrocarbon group of from 8 to 24 carbons, or R¹⁴ and R¹⁵ are hydrocarbon groups of from 8 to 24 carbons while R¹⁶ is a hydrocarbon group of from 1 to 4 carbons. In a most preferred embodiment, the surfactant or surfactants are chosen from alkanol amides, amine oxides, ethoxylated amines, ethoxylated amides and phosphate esters.

[0046] Compounds suitable for use as the anionic surfactant of the present invention are those having polar, solubilizing groups such as carboxylate, sulfonate, sulfate and phosphate. Anionic surfactants are generally known in the art and include, for example, alkyl aryl sulfonates (such as, for example, alkylbenzenesulfonates), alkyl aryl sulfonic acids (such as, for example, sodium and ammonium salts of toluene-, xylene- and isopropylbenzenesulfonic acids), sulfonated amines and sulfonated amides (such as, for example, amidosulfonates), carboxylated alcohols and carboxylated alkylphenol ethoxylates, diphenyl sulfonates, fatty esters, isethionates, lignin-based surfactants, olefin sulfonates (such as, for example, RCH═CHSO₃Na, where R is C₁₀-C₁₆), phosphorous-based surfactants, protein based surfactants, sarcosine-based surfactants (such as, for example, N-acylsarcosinates such as sodium N-lauroylsarcosinate), sulfates and sulfonates of oils and/or fatty acids, sulfates and sulfonates of ethoxylated alkylphenols, sulfates of alcohols, sulfates of ethoxylated alcohols, sulfates of fatty esters, sulfates of aromatic or fluoro containing compounds, sulfosuccinnamates, sulfosuccinates (such as, for example, diamyl-, dioctyl- and diisobutylsulfosuccinates), taurates, and sulfonic acids.

[0047] In a preferred embodiment, one component of the present invention comprises one or more anionic surfactants that may be a sulfosuccinate, sulfate, sulfonate, carboxylate, or phosphorous containing surfactant according to one or more of the structural formulas IX to XIII:

 (R²⁸—OSO₃ _(⁻) )_(q)X⁺  (X)

(R²⁸—SO₃ _(⁻) )_(q)X⁺  (XI)

(R²⁹—CO₂ _(⁻) )_(q)X⁺  (XII)

(R³⁰—OPO₃ _(⁻) )_(q)X⁺  (XIII)

[0048] wherein:

[0049] each R²⁶, R²⁷, R²⁸, R²⁹ and R³⁰ is independently a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic, fluoro containing, an oxygenated alkane or other chalcogen containing radical, and X is H or an alkali metal, alkaline earth element or a chalcogen containing counterion or other suitable cation that does not unduly interfere with the functioning of the molecule as a surfactant where the subscript q is the valence or oxidation state of the cation X. In a preferred embodiment, R²⁶ and R²⁷ are linear hydrocarbon groups of from 4 to 20 carbons, more preferably 6 to 13 carbons, R²⁸ is a hydrocarbon group of from 6 to 20 carbons, more preferably from 8 to 16 carbons, and R²⁹ is a hydrocarbon group of from 8 to 26 carbons, more preferably from 10 to 20 carbons, and R³⁰ is a hydrocarbon of from 8 to 30 carbons.

[0050] Compounds suitable for use as the cationic surfactant of the present invention are those having a positive charge when dissolved in aqueous media, which resides on an amino or quaternary nitrogen. Cationic surfactants are generally known in the art and include, for example, amine acetates, amines (such as, for example, oxygen-free amines such as monoalkylamines, dialkylamines and N-alkyltrimethylene diamines, and oxygen-containing amines such as amine oxides, ethoxylated alkylamines, 1-(2-hydroxyethyl)-2-imidazolines, and alkoxylates of ethylenediamine), and quaternary ammonium salts (such as, for example, dialkyldimethylammonium salts, alkylbenzyldimethylammonium chlorides, alkyltrimethylammonium salts and alkylpyridium halides), and quaternary ammonium esters (such as, for example, diethyl ester dimethyl ammonium chloride).

[0051] In a preferred embodiment, one component of the present invention comprises one or more cationic surfactants that may be a quaternary amine-based surfactant according to the structural formula XIV:

(R³¹R³²R³³R³⁴N⁺)_(p)J⁻  (XIV)

[0052] wherein:

[0053] each R³¹, R³², R³³, and R³⁴ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic, fluoro containing, an oxygenated alkane or other chalcogen containing group, and J is a suitable anion having an oxidation state or valence p that does not unduly interfere with the functioning of the molecule as a surfactant. In a preferred embodiment, R³¹ and R³² are hydrocarbon groups of from 1 to 4 carbons, more preferably, methyl, and R³³ and R³⁴ are hydrocarbon groups of from 6 to 30 carbons, more preferably from 8 to 24 carbons.

[0054] Compounds suitable for use as the amphoteric surfactant of the present invention are those containing both an acidic and basic hydrophilic group. Amphoteric surfactants are compatible with anionic and cationic surfactants. Amphoteric surfactants are generally known in the art and include, for example, betaine derivatives such as alkylbetaines and amidopropylbetaines, block copolymers, imidazolines and lecithins.

[0055] In a preferred embodiment, one component of the present invention comprises one or more amphoteric surfactants according to the structural formula XV:

[0056] wherein:

[0057] each R³⁵, R³⁶ and R³⁷ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic, fluoro containing, an oxygenated alkane or other chalcogen containing group, G is a divalent spacer group, and Y is a carboxylate, sulfonate, sulfate, phosphonate or other similar group. In a preferred embodiment, R³⁵, is a hydrocarbon of from 1 to 4 carbons, and R³⁶ and R³⁷ are hydrocarbons of from 6 to 24 carbons.

[0058] Surfactants are known in the art and are commercially available under many trade names from many sources, such as for example, Akzo Chemical Co., Calgene Chemical Inc., Emkay Chemical Co, Hercules, Inc., ICI Americas Inc., Lonza, Inc., Rhone Poulenc, Inc., Union Carbide Corp. and Witco Corp.

[0059] In a preferred embodiment, the dry cleaning composition of the present invention further comprises a minor amount, preferably, less than 50 pbw per 100 pbw of the composition, more preferably, less than 10 pbw per 100 pbw of the composition, of one or more non-siloxane fluids. Suitable non-siloxane fluids include aqueous fluids, such as, for example, water, and organic fluids, for example, hydrocarbon fluids and halogenated hydrocarbon fluids.

[0060] An article, such as for example, a textile or leather article, typically, a garment, is dry cleaned by contacting the article with the composition of the present invention. In a preferred embodiment, the articles to be cleaned include textiles made from natural fibers, such as for example, cotton, wool, linen and hemp, from synthetic fibers, such as, for example, polyester fibers, polyamide fibers, polypropylene fibers and elastomeric fibers, from blends of natural and synthetic fibers, from natural or synthetic leather or natural or synthetic fur.

[0061] The article and dry cleaning composition are then separated, by, for example, one or more of draining and centrifugation. In a preferred embodiment, separation of the article and dry cleaning composition is followed by the application of heat, preferably, heating to a temperature of from 15° C. to 120° C., preferably from 20° C. to 100° C., or reduced pressure, preferably, a pressure of from 1 mm Hg to 750 mm Hg, or by application of both heat and reduced pressure, to the article.

[0062] Testing for water soluble stain removal was accomplished using fabric swatches supplied by the International Fabricare Institute (“IFI”) (Silver Spring, MD) that contained a water soluble dye. The color change of a swatch of this material was measured by a Minolta CR-300® Colorimeter using the Hunter Color Number difference calculations. The larger the change in Hunter Color Number (ΔE), the greater the dye removal and the more efficient the cleaning.

[0063] The following examples are to illustrate the invention and are not to be construed as limiting the claims.

EXAMPLES

[0064] Testing Procedure:

[0065] Circular swatches (from IFI) containing a water soluble dye were measured by the calorimeter, and the initial color values for L, a and b (as defined by the Hunter Color Numbers) were recorded. The fabric swatches were then placed in vials containing the cleaning composition of the present invention, and the vial was shaken for 10 minutes at ambient temperature. The fabric swatch was removed and allowed to drip dry for 2 to 5 seconds, then placed on absorbent toweling and allowed to air dry for 16 to 24 hours. A second reading of each fabric swatch was taken and the color difference (ΔE) was determined using the following formula:

ΔE=[(L ₁ −L ₂)²+(a ₁ −a ₂)²=(b ₁ −b ₂)²]½

[0066] This color difference represents the relative amount of cleaning, with the higher ΔE indicative of better cleaning performance.

Example 1 Nonionic Surfactants [Ethoxylated Alcohols]

[0067] A cleaning composition according to the present invention containing a cyclic siloxane (D₅) and one or more nonionic surfactants was made. Fabric swatches were cleaned using the above procedure, and the color difference was measured to determine the effectiveness of the cleaning composition. A solution of cyclic siloxane (D₅) without a surfactant was used as a control.

[0068] Nonionic surfactants used in the example are those represented by formula III above, where R⁹ and n are as described in Table 1, and R¹⁰ is H. TABLE 1 Ethoxylated Alcohols Exp. No. R₉ n pbw ΔE  1 C₄ 1 1 1.9  2 C₄ 1 5 2.7  3 C₄ 2 1 3.2  4 C₄ 2 5 3.2  5 C₁₂₋₁₅ 3 1 38.8  6 C₁₂₋₁₅ 3 5 41.1  7 C₁₂₋₁₃ 9 1 37.8  8 C₁₂₋₁₃ 9 5 38.7  9 C₁₂₋₁₃ 6.5 1 39.1 10 C₁₂₋₁₃ 6.5 5 38.7 11 C₁₄₋₁₅ 7 1 2.0 [18.7] 12 C₁₄₋₁₅ 7 5 39.0 [33.7] 13   C₁₂₋₁₃/C₄ 6.5/1 5 (50/50) 41.5 14   C₁₂₋₁₃/C₄ 9/1 5 (50/50) 42.9 15   C₁₂₋₁₅/C₄ 3/1 5 (50/50) 13.8 16   C₁₄₋₁₅/C₄ 7/1 5 (50/50) 41.1 17 C₁₂ 4 1 35.8 18 C₁₂ 4 5 40.7 19 C₁₂ 23 1 0.9 20 C₁₂ 23 5 1.3 21 C₁₆ 2 1 4.6 22 C₁₆ 2 5 2.0 23 C₁₈ 2 1 2.6 24 C₁₈ 2 5 19.0 25 C₁₈ 10 1 2.4 26 C₁₈ 10 5 23.4 27 C₁₈ 20 1 4.0 28 C₁₈ 20 5 22.8 29 C₁₂/C₄ 4/1 5 (50/50) 41.1 39 C₁₂/C₄ 23/1 5 (50/50) 1.6 31 C₁₆/C₄ 2/1 5 (50/50) 3.7 32 C₁₈/C₄ 2/1 5 (50/50) 11.4 33 C₁₈/C₄ 10/1 5 (50/50) 21.1 34 C₁₈/C₄ 20/1 5 (50/50) 34.4 Control 1 — — 0 1.9

[0069] Table 1 shows that nonionic surfactants enhance the cleaning and dye removal of the base cyclic siloxane (D₅) solvent.

Example 2 Anionic Surfactants

[0070] A cleaning composition according to the present invention containing a cyclic siloxane (D₅) and one or more anionic surfactants was made. Fabric swatches were cleaned using the above procedure, and the color difference was measured to determine the effectiveness of the cleaning composition. A solution of cyclic siloxane (D₅) without a surfactant was used as a control. TABLE 2 Sulfosuccinates Exp. Designation* mixture pbw ΔE 35 Aerosol TR — 1 2.8 36 Aerosol TR — 5 6.5 37 Aerosol OT — 1 1.6 38 Aerosol OT — 5 2.3 39 Aerosol GPG — 1 3.0 40 Aerosol GPG — 5 3.0 41 Aerosol TR/OT 50/50 1 1.5 42 Aerosol TR/OT 50/50 5 2.5 43 Aerosol TR/GPG 50/50 1 6.9 44 Aerosol TR/GPG 50/50 5 16.9 45 Aerosol OT/GPG 50/50 1 4.6 46 Aerosol OT/GPG 50/50 5 6.7 Control 2 — — 0 1.9

[0071] Table 2 shows that the anionic sulfosuccinate surfactants enhanced the water soluble dye removal of the base cyclic siloxane (D₅) solvent. (Surfactant TR is a solution in 20% ethanol and 10% water; GPG is a solution in 8% ethanol and 22% water.)

Example 3 Cationic and Anionic Surfactants

[0072] A cleaning composition according to the present invention containing a cyclic siloxane (D₅) and one or more anionic and cationic surfactants was made. Fabric swatches were cleaned using the above procedure, and the color difference was measured to determine the effectiveness of the cleaning composition. A solution of cyclic siloxane (D₅) without a surfactant was used as a control. TABLE 3 Ionic Surfactants (Cationic and Anionic) Exp Type R pbw AB 47 R-SO₄ ⁻Na⁺ C₁₄₋₁₆ 5 11.2 alkene 48 R₂Me₂N⁺Cl− C₁₂ 1 41.5 49 R₂Me₂N⁺Cl− C₁₂ 5 41.2 50 DDBSA — 1 51.5 51 DDBSA — 5 50.4 52 R-PhO-(EO)₃- C₁₂ 1 6.2 OSO₃ ⁻Na⁺ 53 R-PhO-(EO)₃- C₁₂ 5 5.3 OSO₃ ⁻Na⁺ 54 R-SO₄ ⁻Na⁺ C₁₂ 1 2.7 55 R-SO₄ ⁻Na⁺ C₁₂ 5 3.4 Control 3 — — 0 1.9

[0073] Table 3 shows that the ionic surfactants enhanced the water soluble dye removal of the base cyclic siloxane (D₅) solvent. (R₂Me₂N⁺Cl⁻ came as a solution in water.)

Example 4 Nonionic Surfactants with Water

[0074] A cleaning composition according to the present invention containing a cyclic siloxane (D₅), water and a nonionic surfactant was made. Fabric swatches were cleaned using the above procedure, and the color difference was measured to determine the effectiveness of the cleaning composition. A solution of cyclic siloxane (D₅) without a surfactant was used as a control. Nonionic surfactants used in the example are those represented by formula III above, where R⁹ and n are as described in Table 4, and R¹⁰ is H. TABLE 4 Nonionic Surfactants pbw pbw pbw Exp. No. R⁹ n solvent surfactant water ΔE 1 C₁₂₋₁₃ 6.5 95 4 1 39.5 2 C₁₂₋₁₃ 6.5 95 1 4 33.1 3 C₁₂₋₁₃ 6.5 98 1 1 13.8 4 C₁₂₋₁₃ 9 95 4 1 34.9 5 C₁₂₋₁₃ 9 95 1 4 38.3 6 C₁₂₋₁₃ 9 98 1 1 25.5 7 C₁₂₋₁₅ 3 95 4 1 7.7 8 C₁₂₋₁₅ 3 95 1 4 38.3 9 C₁₂₋₁₅ 3 98 1 1 38.9 10 C₁₄₋₁₅ 7 95 4 1 34.5 11 C₁₄₋₁₅ 7 95 1 4 36.4 12 C₁₄₋₁₅ 7 98 1 1 7.9 13 C₁₂   4 95 4 1 17.9 14 C₁₂   4 95 1 4 32.3 15 C₁₂   4 98 1 1 37.4 16 C₁₂   23 95 4 1 24.5 17 C₁₂   23 95 1 4 34.2 18 C₁₂   23 98 1 1 1.5 19 C₁₆   20 95 4 1 25.7 20 C₁₆   20 95 1 4 11.8 21 C₁₆   20 98 1 1 17.4 22 C₁₈   2 95 4 1 8.5 23 C₁₈   2 95 1 4 7.9 24 C₁₈   2 98 1 1 5.5 25 C₁₈   10 95 4 1 16.8 26 C₁₈   10 95 1 4 6.2 27 C₁₈   10 98 1 1 3.7 28 C₁₈   20 95 4 1 13.6 29 C₁₈   20 95 1 4 28.4 30 C₁₈   20 98 1 1 5.3 31 C₄   1 95 4 1 6.2 32 C₄   1 95 1 4 11.7 33 C₄   1 98 1 1 1.0 34 C₄   2 95 4 1 33.9 35 C₄   2 95 1 4 34.1 36 C₄   2 98 1 1 38.7 37 C₁₁₋₁₄ 12 95 4 1 24.1 38 C₁₁₋₁₄ 12 95 1 4 33.1 39 C₁₁₋₁₄ 12 98 1 1 10.2 Control 4 — — 99 0 1 2.2 Control 5 — — 96 0 4 9.5

[0075] TABLE 4A Nonionic Surfactants (Commercially Available) Surfactant pbw pbw pbw Exp. Trade Name n solvent surfactant water ΔE 40 Triton X-405 40 95 4 1 37.7 41 Triton X-405 40 95 1 4 25.5 42 Triton X-405 40 98 1 1 15.9 43 Igepal CA-520  5 95 4 1 4.4 44 Igepal CA-520  5 95 1 4 10.0 45 Igepal CA-520  5 98 1 1 2.3 46 Igepal CO-850 20 95 4 1 4.0 47 Igepal CO-850 20 95 1 4 2.6 48 Igepal CO-850 20 98 1 1 16.2 49 Span-80 — 95 4 1 3.7 50 Span-80 — 95 1 4 2.4 51 Span-80 — 98 1 1 5.2 Control 1 — — 99 0 1 2.2 Control 2 — — 96 0 4 9.5

[0076] Tables 4 and 4A show that nonionic surfactants in the presence of water enhance the cleaning and dye removal of the base cyclic siloxane (D₅) solvent.

Example 5 Ionic Surfactants

[0077] A cleaning composition according to the present invention containing a cyclic siloxane (D5), water and an ionic surfactant was made. Fabric swatches were cleaned using the above procedure, and the color difference was measured to determine the effectiveness of the cleaning composition. A solution of cyclic siloxane (D₅) and water without a surfactant was used as a control. TABLE 5 Ionic Surfactants Surfactant Trade pbw pbw pbw Exp Name solvent surfactant Water ΔE 52 Aerosol OT 95 4 1 6.9 53 Aerosol OT 95 1 4 20.3 54 Aerosol OT 98 1 1 7.5 55 Triton X-200 95 4 1 4.0 56 Triton X-200 95 1 4 36.0 57 Triton X-200 98 1 1 3.3 58 Vari-Soft 300 95 4 1 40.3 59 Vari-Soft 300 95 1 4 38.4 60 Vari-Soft 300 98 1 1 35.9 61 Bio-Soft D-62 95 4 1 2.9 62 Bio-Soft D-62 95 1 4 28.4 63 Bio-Soft D-62 98 1 1 14.3 64 Ethoquad C/25 95 4 1 35.2 65 Ethoquad C/25 95 1 4 34.3 66 Ethoquad C/25 98 1 1 26.3 67 Span-80 95 4 1 3.7 68 Span-80 95 1 4 2.4 69 Span-80 98 1 1 5.2 70 Glucopon 225* 95 1 4 4.7 71 Glucopon 225 95 4 1 31.2 72 Glucopon 225 98 1 1 5.8 73 Glucopon 225 99 1 — 10.8 74 Glucopon 425** 95 1 4 32.5 75 Glucopon 425 95 4 1 36.2 76 Glucopon 425 98 1 1 19.0 77 Glucopon 425 99 1 — 3.9 78 Glucopon 600** 95 1 4 4.3 79 Glucopon 600 95 4 1 27.9 80 Glucopon 600 98 1 1 4.7 81 Glucopon 600 99 1 — 9.3 82 Alkamide S-280 95 5 — 8.4 83 Alkamide S-280 99 1 — 1.7 84 Alkamide S-280 98 1 1 2.0 85 Alkamide CME 95 5 — 7.6 86 Alkamide CME 99 1 — 2.4 87 Alkamide CME 98 1 1 6.6 Control 6 — 99 0 1 2.2 Control 7 — 96 0 4 9.5

[0078] Table 5 shows that the ionic surfactants in the presence of water enhanced the water soluble dye removal of the base cyclic siloxane (D₅) solvent. TABLE 6 Ionic surfactants with and without water pbw pbw pbw Exp solvent Surfactant surfactant Water ΔE 88 14.25 Cocoa/oleamidopropyl betaine (30% in water) 0.75 — 14.39 89 14.85 Cocoa/oleamidopropyl betaine (30% in water) 0.15 — 16.76 90 14.7 Cocoa/oleamidopropyl betaine (30% in water) 0.15 0.15 32.02 91 14.25 Cocomidopropyl betaine (29% in water) 0.6 — 31.20 92 14.85 Cocomidopropyl betaine (29% in water) 0.15 — 7.11 93 14.7 Cocomidopropyl betaine (29% in water) 0.15 0.15 29.80 94 14.25 Stearic acid monoethanolamide 0.6 — 8.37 95 14.85 Stearic acid monoethanolamide 0.15 — 1.72 96 14.7 Stearic acid monoethanolamide 0.15 0.15 1.96 97 14.25 Amphoteric surfactant (50% in water) 0.6 — 33.76 98 14.85 Amphoteric surfactant (50% in water) 0.15 — 24.95 99 14.7 Amphoteric surfactant (50% in water) 0.15 0.15 32.09 100 14.25 Coconut fatty acid monoethanolamide 0.6 — 7.61 101 14.85 Coconut fatty acid monoethanolamide 0.15 — 2.40 102 14.7 Coconut fatty acid monoethanolamide 0.15 0.15 6.59 103 14.25 1,2-hexanediol 0.6 — 3.86 104 14.85 1,2-hexanediol 0.15 — 21.40 105 14.7 1,2-hexanediol 0.15 0.15 14.85 106 14.85 Di(ethyleneglycol)-2-ethylhexyl ether 0.15 — 8.03 107 14.25 Di(ethyleneglycol)-2-ethylhexyl ether 0.75 — 10.40 108 14.25 Di(ethyleneglycol)-2-ethylhexyl ether 0.6 0.15 9.85 109 14.25 Di(ethyleneglycol)-2-ethylhexyl ether 0.15 0.6  13.97 110 14.7 Di(ethyleneglycol)-2-ethylhexyl ether 0.15 0.15 22.73 111 14.85 Di(ethyleneglycol)hexyl ether 0.15 — 8.89 112 14.25 Di(ethyleneglycol)hexyl ether 0.75 — 9.13 113 14.25 Di(ethyleneglycol)hexyl ether 0.6 0.15 33.40 114 14.25 Di(ethyleneglycol)hexyl ether 0.15 0.6  16.64 115 14.7 Di(ethyleneglycol)hexyl ether 0.15 0.15 24.02 116 14.85 Didecyldimethylammonium bromide 0.15 — 16.55 117 14.25 Didecyldimethylammonium bromide 0.75 — 15.44 118 14.25 Didecyldimethylammonium bromide 0.6 0.15 4.78 119 14.25 Didecyldimethylammonium bromide 0.15 0.6  10.36 120 14.7 Didecyldimethylammonium bromide 0.15 0.15 10.88 121 14.85 Dihexadecyldimethylammonium bromide 0.15 — 12.53 122 14.25 Dihexadecyldimethylammonium bromide 0.75 — 12.15 123 14.25 Dihexadecyldimethylammonium bromide 0.6 0.15 8.73 124 14.25 Dihexadecyldimethylammonium bromide 0.15 0.6  9.56 125 14.7 Dihexadecyldimethylammonium bromide 0.15 0.15 9.45 126 14.85 Cetyltrimethylammonium bromide 0.15 — 13.03 127 14.25 Cetyltrimethylammonium bromide 0.75 — 14.79 128 14.25 Cetyltrimethylammonium bromide 0.6 0.15 12.25 129 14.25 Cetyltrimethylammonium bromide 0.15 0.6  38.27 130 14.7 Cetyltrimethylammonium bromide 0.15 0.15 10.39 131 14.85 1,2-butanediol 0.15 — 26.14 132 14.25 1,2-butanediol 0.75 — 33.45 133 14.7 1,2-butanediol 0.15 0.15 21.40 134 14.85 1,2-decanediol 0.15 — 11.26 135 14.25 1,2-decanediol 0.75 — 29.54 136 14.7 1,2-decanediol 0.15 0.15 11.55 137 14.85 1,2-hexanediol 0.15 — 10.01 138 14.25 1,2-hexanediol 0.75 — 28.56 139 14.7 1,2-hexanediol 0.15 0.15 32.51 140 14.85 1,6-hexanediol 0.15 — 7.47 141 14.25 1,6-hexanediol 0.75 — 5.16 142 14.7 1,6-hexanediol 0.15 0.15 31.78 143 14.85 1,10-decanediol 0.15 — 5.82 144 14.25 1,10-decanediol 0.75 — 1.22 145 14.7 1,10-decanediol 0.15 0.15 8.33

[0079] Table 7 shows the variations in R and x that were explored for these surfactants. Mixtures of materials within a class were also examined as seen in experiments 13-16 and 29-34. None of these surfactants were soluble in D5 in the ranges examined but some were only slightly hazy. As seen in Table 1, the surfactants with R=C₁₂₋₁₅ and x=3-9 repeat units gave the best cleaning. TABLE 7 Ethoxylated Alcohols. Exp. Surfactant R n pbw ΔE 146 06383 C₄ 1 1 1.9 147 C₄ 1 5 2.7 148 2-(2-n-butoxy C₄ 2 1 3.2 ethoxy)ethanol 149 067012 C₄ 2 5 3.2 150 Neodol 25-3 C₁₂₋₁₅ 3 1 38.8 151 C₁₂₋₁₅ 3 5 41.9 152 Neodol 23-9 C₁₂₋₁₃ 9 1 37.8 153 C₁₂₋₁₃ 9 5 38.7 154 Neodol 23-6.5 C₁₂₋₁₃ 6.5 1 39.1 155 C₁₂₋₁₃ 6.5 5 38.6 156 Neodol 45-7 C₁₄₋₁₅ 7 1 18.7 157 C₁₄₋₁₅ 7 5 36.7 158 C₁₄₋₁₅ 7 5 30.7 159 C₁₂₋₁₃/C₄ 6.5/1 5 (50/50) 41.5 160 C₁₂₋₁₃/C₄ 9/1 5 (50/50) 42.9 161 C₁₂₋₁₅/C₄ 3/1 5 (50/50) 13.8 162 C₁₄₋₁₅/C₄ 7/1 5 (50/50) 41.1 163 BRIJ 30 C₁₂ 4 1 35.8 164 067220 C₁₂ 4 5 40.7 165 BRIJ 35 C₁₂ 23 1 0.9 166 067219 C₁₂ 23 5 1.3 167 BRIJ 58 C₁₆ 20 1 4.6 168 C₁₆ 20 5 2.0 169 BRIJ 72 C₁₈ 2 1 2.6 170 067263 C₁₈ 2 5 19.0 171 BRIJ 76 C₁₈ 10 1 2.4 172 067262 C₁₈ 10 5 23.4 173 BRIJ 78 C₁₈ 20 1 4.0 174 C₁₈ 20 5 22.8 175 C₁₂/C₄ 4/1 5 (50/50) 41.1 176 C₁₂/C₄ 23/1 5 (50/50) 1.6 177 C₁₆/C₄ 2/1 5 (50/50) 3.7 178 C₁₈/C₄ 2/1 5 (50/50) 11.4 179 C₁₈/C₄ 10/1 5 (50/50) 21.1 180 C₁₈/C₄ 20/1 5 (50/50) 34.4 Control 1 — — 0 1.9

[0080] When similar compositions of 1 and D₅ with water were examined, again, the best cleaning was seen with R=C₁₂₋₁₅ and x=3-9 repeat units (Table 2). TABLE 2 Ethoxylated Alcohols with Water. pbw Exp. pbw sur- pbw No. Surfactant R n solvent factant water ΔE 35 Neodol 23-6.5 C₁₂₋₁₃ 6.5 95 4 1 39.5 36 C₁₂₋₁₃ 6.5 95 1 4 33.1 37 C₁₂₋₁₃ 6.5 98 1 1 13.8 38 Neodol 23-9 C₁₂₋₁₃ 9 95 4 1 34.9 39 C₁₂₋₁₃ 9 95 1 4 38.3 40 C₁₂₋₁₃ 9 98 1 1 25.5 41 Neodol 25-3 C₁₂₋₁₅ 3 95 4 1 7.7 42 C₁₂₋₁₅ 3 95 1 4 38.3 43 C₁₂₋₁₅ 3 98 1 1 38.9 44 Neodol 45-7 C₁₄₋₁₅ 7 95 4 1 34.5 45 C₁₄₋₁₅ 7 95 1 4 36.4 46 C₁₄₋₁₅ 7 98 1 1 7.9 47 BRIJ 30 C₁₂ 4 95 4 1 17.9 48 C₁₂ 4 95 1 4 32.3 49 C₁₂ 4 98 1 1 37.4 50 BRIJ 35 C₁₂ 23 95 4 1 24.5 51 C₁₂ 23 95 1 4 34.2 52 C₁₂ 23 98 1 1 1.5 53 BRIJ 58 C₁₆ 20 95 4 1 25.7 54 C₁₆ 20 95 1 4 11.8 55 C₁₆ 20 98 1 1 17.4 56 BRIJ 72 C₁₈ 2 95 4 1 8.5 57 C₁₈ 2 95 1 4 7.9 58 C₁₈ 2 98 1 1 5.5 59 BRIJ 76 C₁₈ 10 95 4 1 16.8 60 C₁₈ 10 95 1 4 6.2 61 C₁₈ 10 98 1 1 3.7 62 BRIJ 78 C₁₈ 20 95 4 1 13.6 63 C₁₈ 20 95 1 4 28.4 64 C₁₈ 20 98 1 1 5.3 65 06383 C₄ 1 95 4 1 6.2 66 C₄ 1 95 1 4 11.7 67 C₄ 1 98 1 1 1.0 68 067012 C₄ 2 95 4 1 33.9 69 C₄ 2 95 1 4 34.1 70 C₄ 2 98 1 1 38.7 71 C₁₁₋₁₄ 12 95 4 1 24.1 72 C₁₁₋₁₄ 12 95 1 4 33.1 73 C₁₁₋₁₄ 12 98 1 1 10.2 Con- — — 95 0 1 5.3 trol 2 Con- — — 99 0 4 2.9 trol 3 Con- — — 99 0 5 2.6 trol 4

[0081] Ethoxylated phenols, 2, were also explored (Table 3). The most effective mixtures included longer EO chains and lower amounts of water.

TABLE 3 Alkyl Phenol Surfactants. pbw pbw pbw Exp. Surfactant R n solvent surfactant water ΔE 74 Triton X-405 C₉ 40 95 4 1 37.7 75 40 95 1 4 25.5 76 40 98 1 1 15.9 77 Igepal CA-520 C₁₂ 5 95 4 1 4.4 78 5 95 1 4 10.0 79 5 98 1 1 2.3 80 Igepal CO-850 C₉ 20 95 4 1 4.0 81 20 95 1 4 2.6 82 20 98 1 1 16.2

[0082] Glycol ethers and diols were also examined as additives to enhance the cleaning ability of the silicone solvent as seen in Table 4. TABLE 4 Non-Ionic Ether and Diol Surfactants. Exp. pbw pbw pbw No. Surfactant solvent surfactant water ΔE 83 AZ7989 di(ethylene- 99 1 — 8.03 glycol)-2-ethyl- hexyl ether 84 95 5 — 10.40 85 95 4 1 9.85 86 95 1 4 13.97 87 98 1 1 22.73 88 AZ7988 di(ethylene- 99 1 — 8.89 glycol)hexyl ether 89 95 5 — 9.13 90 95 4 1 33.40 91 95 1 4 16.64 92 98 1 1 24.02 93 AZ7997 1,2-butanediol 99 1 — 26.14 94 95 5 — 33.45 95 98 1 1 21.40 96 AZ7998 1,2-decanediol 99 1 — 11.26 97 95 5 — 29.54 98 98 1 1 11.55 99 AZ7995 1,2-hexanediol 99 1 — 10.01 100 95 5 — 28.56 101 95 5 — 15.7 102 98 1 1 32.51 103 99 1 — 21.40 104 98 1 1 14.85 105 AZ7996 1,6-hexanediol 99 1 — 7.47 106 95 5 — 5.16 107 98 1 1 31.78 108 AZ7999 1,10-decanediol 99 1 — 5.82 109 95 5 — 1.22 110 98 1 1 8.33

[0083] In the ether examples, optimal performance was seen with the addition of small amounts of water. The 1,2-diols were efficient at removing the dye at the 5% level, although significant cleaning was seen at 1% with water present.

[0084] Table 5 shows the results from using sugar based surfactants and alkanol amides as water-based stain removers.

TABLE 5 Other Non-Ionic Surfactants. Exp. Surfactant Trade pbw pbw pbw No. Name R solvent surfactant water ΔE 111 Span-80 Oleic 95 4 1 3.7 112 95 1 4 2.4 113 98 1 1 5.2 114 Glucopon 225* C₈₋₁₀ 95 1 4 4.7 115 95 4 1 31.2 116 98 1 1 5.8 117 99 1 — 10.8 118 Glucopon 425** C₈₋₁₆ 95 1 4 32.5 119 95 4 1 36.2 120 98 1 1 19.0 121 99 1 — 3.9 122 95 5 — 19.6 123 Glucopon 600*** C₁₀₋₁₆ 95 1 4 4.3 124 95 4 1 27.9 125 98 1 1 4.7 126 99 1 — 9.3 127 Alkamide S-280 Stearic 95 5 — 8.37 128 99 1 — 1.72 129 98 1 1 1.96 130 Alkamide CME Coconut 95 5 — 7.61 131 99 1 — 2.40 132 98 1 1 6.59

[0085] The sorbitan oleate, as Span 80, was fairly ineffective as a cleaning additive, but the 6-membered gludcoside materials (Glucopans) exhibited good cleaning power at the 4% level with additional water. The two alkanol amides performed poorly as cleaning surfactants in these tests.

[0086] Cationics

[0087] The cationic surfactants tested were all quaternary ammonium salts of the type 6 below. As one can see, the quat salts were effective at the 1% level in all cases. Additional water was sometimes advantageous.

TABLE 6 Cationic Surfactants. Exp. pbw pbw pbw No. Surfactant solvent surfactant water ΔE 133 AZ7987 Didecyldimethyl 99 1 — 16.55 ammonium bromide 134 95 5 — 15.44 135 95 4 1 4.78 136 95 1 4 10.36 137 98 1 1 10.88 138 AZ7990 Dihexadecyldi- 99 1 — 12.53 methyl ammonium bromide 139 95 5 — 12.15 140 95 4 1 8.73 141 95 1 4 9.56 142 98 1 1 9.45 143 AZ7991 cetyltrimethyl- 99 1 — 13.03 ammonium bromide 144 95 5 — 14.79 145 95 4 1 12.25 146 95 1 4 38.27 147 98 1 1 10.39 148 Vari-Soft 300 95 4 1 40.3 149 95 1 4 38.4 150 98 1 1 35.9 151 06955 Ethoquad C/25 95 4 1 35.2 152 95 1 4 34.3 153 98 1 1 26.3 154 99 1 — 41.5 155 95 5 — 41.2

[0088] Amphoterics

[0089] The amphoteric materials examined were of the betaine class as illustrated below (table 7). These were quaternized glycine derivatives. All these materials were supplied as aqueous solutions and performed moderately well at high levels and even better at lower, 1% loading.

TABLE 7 Amphoteric Surfactants. Exp. pbw pbw pbw No. Surfactant R solvent surfactant water ?E 156 Mirataine COB* Coco/oleo 95 5 — 14.39 157 99 1 — 16.76 158 98 1 1 32.02 159 Mirataine Coco 95 5 — 31.20 BET-C30** 160 99 1 — 7.11 161 98 1 1 29.80 162 Mirataine 95 5 — 33.76 JC HA*** 163 99 1 — 24.95 164 98 1 1 32.09

[0090] Anionics

[0091] A wide variety of organic anionic surfactants are available in the forms of sulfosuccinates, sulfonates, phosphonates and the like. One set examined were the sulfosuccinates as shown in Table 8. Best results were seen with high levels of added water. One beneficial feature of the Aerosol OT was that it was soluble in D₅ to at least 5 weight percent.

TABLE 8 Sulfosuccinates. Surfactant pbw pbw pbw Exp. Trade Name R mixture solvent surf water ΔE 165 Aerosol TR Tridecyl — 99 1 — 2.8 166 — 95 5 — 6.5 167 Aerosol OT Octyl — 99 1 — 1.6 168 — 95 5 — 2.3 169 — 95 4 1 6.9 170 — 95 1 4 20.3 171 — 98 1 1 7.5 172 Aerosol GPG Octyl — 99 1 — 3.0 173 — 95 5 — 3.0 174 Aerosol TR/OT 50/50 99 1 — 1.5 175 50/50 95 5 — 2.5 176 Aerosol TR/GPG 50/50 99 1 — 6.9 177 50/50 95 5 — 16.9 178 Aerosol OT/GPG 50/50 99 1 — 4.6 179 50/50 95 5 — 6.7

[0092] Several phosphorous containing surfactants were tested as shown in Table 9. The ethoxylated phosphonates exhibited modest cleaning behavior while the lecithin-based surfactants did not remove the water soluble dye from the swatch. TABLE 9 Phosphorous Containing Anionic Surfactants. Exp. Surfactant Pbw pbw pbw No. Trade Name Solvent surfactant water ΔE 180 ATPHOS 325O 99 1 — 11.5 181 95 5 — 12.3 182 95 4 1 7.9 183 95 1 4 10.1 184 98 1 1 13.5 185 ATPHOS 3226 99 1 — 12.2 186 95 5 — 11.4 187 95 4 1 11.9 188 95 1 4 6.8 189 98 1 1 4.7 190 YELKIN TS 99 1 — 6.8 191 95 5 — 20.7 192 95 4 1 7.5 193 95 1 4 8.2 194 98 1 1 4.9 195 Ultralec F 99 1 — 1.9 196 95 5 — 1.4 197 95 4 1 1.7 198 95 1 4 1.8 199 98 1 1 3.3

[0093] Alkyl and aryl sulfonates were also explored as surfactants for the silicone solvent. Table 10 shows the results of such materials, with and without additional water. TABLE 10 Other Anionic Surfactants. Surfactant pbw pbw pbw Exp Surfactant Trade Name solvent surfactant Water ΔE 200 AZ6005 Witconate AOS 95 5 — 11.9 201 95 5 — 3.9 202 99 1 — 9.7 203 99 1 — 11.2 204 99 1 — 11.8 205 99 1 — 6.4 206 99 1 — 18.3 207 99 1 — 8.2 208 06417 C₁₂—SO₄ ⁻Na⁺ 99 1 — 2.7 209 95 5 — 3.4 210 06206 Triton X-200 99 1 — 6.2 211 95 5 — 5.3 212 95 4 1 11.6 213 95 1 4 4.8 214 98 1 1 19.0 215 06651 DDBSA 99 1 — 51.5 216 95 5 — 50.4 217 95 4 1 52.3 218 95 1 4 47.4 219 98 1 1 49.1 220 067751 Bio-Soft D-62 95 4 1 2.9 221 95 1 4 28.4 222 98 1 1 14.3

[0094] Fluoro-surfactants were also examined as shown in Table 11. Of all the varieties tried, the fluorinated quat salts and the fluoroalkyl alkoxide displayed the best performance. TABLE 11 Fluoro-Surfactants. Exp. Surfactant pbw pbw pbw No. Trade Name Type solvent surfactant water ΔE 223 Fluorad FC-120 F_(2n+1),C_(n),SO₃ ⁻NR₄ ⁺ 99 1 — 8.5 224 Fluorad FC-120 98 1 1 8.1 225 Fluorad FC-129 F_(2n+1)C_(n),COO^(−K) ⁺ 99 1 − 1.9 226 Fluorad FC-129 98 1 1 7.4 227 Fluorad FC-135 (F_(2n+1)C_(n))₄N^(+I) ⁻ 99 1 — 13.0 228 Fluorad FC-135 98 1 1 31.9 229 Fluorad FC-170C F_(2n+1)C_(n)-(EO)_(x)-H 99 1 — 10.6 230 Fluorad FC-170C 98 1 1 13.0 231 Fluorad FC-171 F_(2n+1)C_(n)—OR 99 1 — 7.5 232 Fluorad FC-171 98 1 1 21.7 233 Fluorad FC-430 F_(2n+1)C_(n)—COOR 99 1 — 10.9 234 Fluorad FC-430 98 1 1 10.4 235 Fluorad FC-740 F_(2n+1)C_(n)—COOR 99 1 — 2.2 236 Fluorad FC-740 98 1 1 3.9 237 Dynol 604 F_(2n+1)C_(n)SO₂N(Et)CH₂COO⁻K⁺ 99 1 — 7.1 238 Dynol 604 98 1 1 1.2

[0095] The present invention exhibits improved performance of dry cleaning agents for stain removal, particularly water soluble stains, through the addition of a surfactant, and optionally water. 

1. A dry cleaning composition, comprising a volatile cyclic, linear or branched siloxane, or combination thereof, and one or more organic surfactants.
 2. The composition of claim 1, comprising from about 90 to about 99.99 parts by weight of the volatile siloxane and from about 0.001 to less than 10 parts by weight of the surfactant or combination of surfactants.
 3. The composition of claim 2, further comprising from about 0.01 to about 15 parts by weight of water.
 4. The composition of claim 1, wherein the surfactant or surfactants are selected from the classes of nonionic, cationic, anionic and amphoteric surfactants.
 5. The composition of claim 1, wherein the organic surfactant comprises a mixture of two or more compatible surfactants of the same or different classes.
 6. The composition of claim 1, wherein the organic surfactant is a nonionic surfactant.
 7. The composition of claim 6, wherein the surfactant comprises one or more nonionic surfactants according to one or more of the structural formulas III and IV: R⁹—O—(CH₂—CH₂—O)_(n)—R¹⁰  (III) R⁹—O—(CH₂—C(CH₃)H—O)_(n)—R¹⁰  (IV) wherein: R⁹ is a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, branched, unsaturated, aromatic and fluoro containing hydrocarbon radicals, R¹⁰ is hydrogen or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, branched, unsaturated, aromatic and fluoro containing hydrocarbon radicals, and n is from about 1 to about
 100. 8. The composition of claim 8, wherein R⁹ contains from 2 to about 24 carbons, R¹⁰ is H and n is from about 2 to about
 20. 9. The composition of claim 6, wherein the surfactant comprises one or more nonionic surfactants according to one or more of the structural formulas V and VI:

wherein: each R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals.
 10. The composition of claim 9, wherein R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ are each H or a hydrocarbon group of 1 to 24 carbons.
 11. The composition of claim 10, wherein one of R¹⁷ and R²⁰ is a hydrocarbon of from 8 to 24 carbons while the other is H or a hydrocarbon of from 1 to 4 carbons, such as —CH₂OH or —CH₂CH₃, and one of R²¹ and R²⁵ is H or a hydrocarbon of from 8 to 24 carbons while the other is a hydrocarbon of from 1 to 4 carbons, such as —CH₂OH or —CH₂CH₃.
 12. The composition of claim 11, wherein the nonionic surfactant or surfactants are chosen from sucrose esters, glucose esters, monoglycerides, polysaccharide ethers and sorbitan-based surfactants.
 13. The composition of claim 6, wherein the surfactant comprises one or more nonionic surfactants selected from the group consisting of an amine-based surfactant and a phosphate ester-based surfactant according to the structural formulas VII and VIII:

each R¹¹, R¹², R¹³, R¹⁴, R¹⁵, and R¹⁶ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, branched, unsaturated, aromatic, and fluoro containing hydrocarbon radicals and chalcogen containing hydrocarbon radicals.
 14. The composition of claim 13, wherein two of R¹¹, R¹² and R¹³, are H or hydrocarbon groups of 1 to 4 carbons, and one is a hydrocarbon group of from 8 to 24 carbons, and R¹⁴ and R¹⁵ are either H or hydrocarbon groups of from 1 to 4 carbons while R¹⁶ is a hydrocarbon group of from 8 to 24 carbons, or R¹⁴ and R¹⁵ are hydrocarbon groups of from 8 to 24 carbons while R¹⁶ is a hydrocarbon group of from 1 to 4 carbons.
 15. The composition of claim 14, wherein the nonionic surfactant or surfactants are chosen from alkanol amides, amine oxides, ethoxylated amines, ethoxylated amides and phosphate esters.
 16. The composition of claim 1, wherein the organic surfactant is an anionic surfactant.
 17. The composition of claim 16, wherein the surfactant comprises one or more anionic surfactants selected from the group consisting of a sulfosuccinate, sulfate, sulfonate, carboxylate, or phosphorous containing surfactant according to the structural formulas IX to XIII:

(R²⁸—OSO₃ _(⁻) )_(q)X⁺  (X) (R²⁸—SO₃ _(⁻) )_(q)X⁺  (XI) (R²⁹—CO₂ _(⁻) )_(q)X⁺  (XII) (R³⁰—OPO₃ _(⁻) )_(q)X⁺  (XIII) wherein: each R²⁶, R²⁷, R²⁸, R²⁹ and R³⁰ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, and X is a cation selected from the group consisting of H, alkali metals, alkaline earth metals or chalcogen containing cations wherein q is the oxidation state or valence of X and whereby X does not unduly interfere with the functioning of the molecule as a surfactant.
 18. The composition of claim 17, wherein R²⁶ and R²⁷ are linear hydrocarbon groups of from 4 to 20 carbons, R²⁸ is a hydrocarbon group of from 6 to 20 carbons, R²⁹ is a hydrocarbon group of from 8 to 26 carbons, and R³⁰ is a hydrocarbon of from 8 to 30 carbons.
 19. The composition of claim 18, wherein R²⁶ and R²⁷ are linear hydrocarbon groups of from 6 to 13 carbons, R²⁸ is a hydrocarbon group of from 8 to 16 carbons, and R²⁹ is a hydrocarbon group of from 10 to 20 carbons.
 20. The composition of claim 1, wherein the organic surfactant is a cationic surfactant.
 21. The composition of claim 20, wherein the surfactant comprises one or more cationic surfactants that may be a quaternary amine-based surfactant according to the structural formula XIV: (R³¹R³²R³³R³⁴N⁺)_(p)J⁻  (XIV) wherein: each R³¹, R³², R³³, and R³⁴ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, and j is a suitable anion having a valence or oxidation state p that does not unduly interfere with the functioning of the molecule as a surfactant.
 22. The composition of claim 21, wherein R³¹ and R³² are hydrocarbon groups of from 1 to 4 carbons, and R³³ and R³⁴ are hydrocarbon groups of from 6 to 30 carbons.
 23. The composition of claim 22, wherein R³¹ and R³² are methyl, and R³³ and R³⁴ are hydrocarbon groups of from 8 to 24 carbons.
 24. The composition of claim 1, wherein the organic surfactant is an amphoteric surfactant.
 25. The composition of claim 24, wherein the surfactant comprises one or more amphoteric surfactants according to the structural formula XV:

wherein: each R³⁵, R³⁶ and R³⁷ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, G is a divalent spacer group, and Y is a carboxylate, sulfonate, sulfate, phosphonate or other similar group.
 26. The composition of claim 25, wherein R³⁵ is a hydrocarbon of from 1 to 4 carbons, and R³⁶ and R³⁷ are hydrocarbons of from 6 to 24 carbons.
 27. The composition of claim 1, wherein the linear or branched, volatile siloxane comprises one or more compounds of the structural formula: M_(2+y+2z)D_(x)T_(y)Q_(z) wherein: M is R¹ ₃SiO_(½); D is R²R³SiO_({fraction (2/2)}); T is R⁴SiO_({fraction (3/2)}); and Q is SiO_({fraction (4/2)}) R¹, R², R³ and R⁴ are each independently a monovalent hydrocarbon radical; and x and y are each integers, wherein 0≦x≦10 and 0≦y≦10 and 0≦z≦10.
 28. The composition of claim 1, wherein the cyclic siloxane component comprises one or more compounds of the structural formula:

wherein: R⁵, R⁶, R⁷ and R⁸ are each independently a monovalent hydrocarbon group; and a and b are each integers wherein 0≦a≦10 and 0≦b≦10, provided that 3≦(a+b)≦10.
 29. A method for dry cleaning an article, comprising contacting the article with a composition comprising a cyclic, linear or branched siloxane and one or more organic surfactants selected from the classes of nonionic, cationic, anionic and amphoteric surfactants.
 30. The method of claim 29, wherein the surfactant comprises one or more nonionic surfactants according to one or more of the structural formulas III and IV: R⁹—O—(CH₂—CH₂—O)_(n)—R¹⁰  (III) R⁹—O—(CH₂—C(CH₃)H—O)_(n)—R¹⁰  (IV) wherein: R⁹ is a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic or fluoro containing, R¹⁰ is hydrogen or a monovalent hydrocarbon group of 1 to 30 carbons that may be linear, cyclic, branched, unsaturated, aromatic or fluoro containing, and n is from about 1 to about
 100. 31. The method of claim 29, wherein the surfactant comprises one or more nonionic surfactants according to one or more of the structural formulas V and VI:

wherein: each R¹⁷, R¹⁸, R¹⁹, R²⁰, R²¹, R²², R²³, R²⁴ and R²⁵ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals.
 32. The method of claim 29, wherein the surfactant comprises one or more nonionic surfactants that may be an amine-based or phosphate ester-based surfactant according to one or more of the structural formulas VII and VIII:

each R¹¹, R¹², R¹³, R¹⁴, R¹⁵, and R¹⁶ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals.
 33. The method of claim 29, wherein the surfactant comprises one or more anionic surfactants that may be a sulfosuccinate, sulfate, sulfonate, carboxylate, or phosphorous containing surfactant according to one or more of the structural formulas IX to XIII:

(R²⁸—OSO₃ _(⁻) )_(q)X⁺  (X) (R²⁸—SO₃ _(⁻) )_(q)X⁺  (XI) (R²⁹—CO₂ _(⁻) )_(q)X⁺  (XII) (R³⁰—OPO₃ _(⁻) )_(q)X⁺  (XIII) wherein: each R²⁶, R²⁷, R²⁸, R²⁹ and R³⁰ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, and X is a cation selected from the group consisting of H, alkali metals, alkaline earth metals or chalcogen containing cations wherein q is the oxidation state or valence of X and whereby X does not unduly interfere with the functioning of the molecule as a surfactant.
 34. The method of claim 29, wherein the surfactant comprises one or more cationic surfactants that may be a quaternary amine-based surfactant according to the structural formula XIV: (R³¹R³²R³³R³⁴N⁺)_(p)J⁻  (XIV) wherein: each R³¹, R³², R³³, and R³⁴ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, and J is a suitable anion having a valence or oxidation state p that does not unduly interfere with the functioning of the molecule as a surfactant.
 35. The method of claim 29, wherein the surfactant comprises one or more amphoteric surfactants according to the structural formula XV:

wherein: each R³⁵, R³⁶ and R³⁷ is independently H or a monovalent hydrocarbon group of 1 to 30 carbons selected from the group consisting of linear, cyclic, and branched hydrocarbon radicals and linear, cyclic and branched chalcogen containing hydrocarbon radicals, G is a divalent spacer group, and Y is a carboxylate, sulfonate, sulfate, phosphonate or other similar group. 